Standard Test Method for Total Carbon, Inorganic Carbon, and Organic Carbon in Water by Ultraviolet, Persulfate Oxidation, and Membrane Conductivity Detection
|Publication Date:||10 July 2002|
|ICS Code (Examination of water for chemical substances):||13.060.50|
This test method covers the determination of total carbon (TC), inorganic carbon (IC), and total organic carbon (TOC) in water in the range from 0.5 to 30 mg/L of carbon. Higher levels may be determined by sample dilution. The test method utilizes ultraviolet-persulfa
This test method has the advantage of a very high sensitivity detector that allows very low detection levels on relatively small volumes of sample. Also, use of two measurement channels allows determination of CO2 in the sample independently of organic carbon. Isolation of the conductivity detector from the sample by the CO2 selective membrane results in a very stable calibration, with minimal interferences.
This test method was used successfully with reagent water spiked with sodium bicarbonate and various organic materials. It is the user's responsibility to ensure the validity of this test method for waters of untested matrices.
This test method is applicable only to carbonaceous matter in the sample that can be introduced into the reaction zone. The injector opening size generally limits the maximum size of particles that can be introduced.
In addition to laboratory analyses, this test method may be applied to on line monitoring.
The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.