5.1 This test method is applicable to cementitious mixtures that have not been exposed to external chloride ions, other than the negligible quantity of chloride ion exposure from sample preparation using potable water, prior to the test.

5.2 The calculation procedure described in this test method is applicable only to laboratory test specimens exposed to a sodium chloride solution as described in this test method. This calculation procedure is not applicable to specimens exposed to chloride ions during cyclic wetting and drying.

Note 1: The diffusion of ionic species in concrete occurs within the fluid-filled pores, cracks and void spaces. The concentration and valence of other ionic species in the pore fluid also influence the rate of chloride diffusion, and therefore, the apparent diffusion coefficient as determined by this test procedure.

5.3 In most cases, the value of the apparent chloride diffusion coefficient for cementitious mixtures changes over time (see Note 2). Therefore, apparent diffusion coefficients obtained at early ages may not be representative of performance in service.

Note 2: The rate of change of the apparent diffusion coefficient for cementitious mixtures containing pozzolans or blast-furnace slag is typically different than that for mixtures containing only portland cement.

5.4 The apparent chloride diffusion coefficient is used in Fick's second law of diffusion to estimate chloride penetration into cementitious mixtures that are in a saturated condition.

5.5 The apparent chloride diffusion coefficient is commonly used in chloride ingress models based on Fick's second law of diffusion. The apparent diffusion coefficient determined by this method includes bound chloride, so proper use of the apparent chloride diffusion coefficient to predict chloride ingress requires consideration of chloride binding.

5.6 The resistance to chloride penetration is affected by such factors as the environment, finishing, mixture composition, workmanship, curing, and age.