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ASTM International - ASTM D5523-04

Standard Test Method for Polyurethane Raw Materials Acidity by Argentometric Determination of Hydrolyzable Chlorine in Monomeric, Aromatic Isocyanates

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Organization: ASTM International
Publication Date: 1 October 2004
Status: inactive
Page Count: 3
ICS Code (Thermoplastic materials): 83.080.20
significance And Use:

This test method can be used for research or for quality control to characterize TDI and MDI.

This test method was developed to overcome problems with low-level acidity determinations that... View More

scope:

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1.1 This test method measures the hydrolyzable chlorine content of monomeric, aromatic isocyanates used as polyurethane raw materials and expresses it as HCl acidity. The test method is applicable to toluene diisocyanate (TDI) and monomeric methylene-bis-(4-phenylisocyanate), known as MDI. The main sources of hydrolyzable chlorine and, therefore, acidity in monomeric aromatic isocyanates are carbamyl chlorides, acid chlorides, and dissolved phosgene. All of these compounds react with alcohols and water to form hydrochloric acid.

1.2 This test method applies only to monomeric isocyanates in which all of the acidity is derived from species that generate HCl on solvolysis.

1.3 The values stated in SI units are to be regarded as the standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Note 1-There is no equivalent ISO standard.

Document History

January 15, 2021
Standard Test Method for Polyurethane Raw Materials: Acidity by Argentometric Determination of Hydrolyzable Chlorine in Monomeric, Aromatic Isocyanates
1.1 This test method measures the hydrolyzable chlorine content of monomeric, aromatic isocyanates used as polyurethane raw materials and expresses it as HCl acidity. The test method is applicable to...
April 1, 2015
Standard Test Method for Polyurethane Raw Materials: Acidity by Argentometric Determination of Hydrolyzable Chlorine in Monomeric, Aromatic Isocyanates
1.1 This test method measures the hydrolyzable chlorine content of monomeric, aromatic isocyanates used as polyurethane raw materials and expresses it as HCl acidity. The test method is applicable to...
August 1, 2010
Standard Test Method for Polyurethane Raw Materials Acidity by Argentometric Determination of Hydrolyzable Chlorine in Monomeric, Aromatic Isocyanates
1.1 This test method measures the hydrolyzable chlorine content of monomeric, aromatic isocyanates used as polyurethane raw materials and expresses it as HCl acidity. The test method is applicable to...
ASTM D5523-04
October 1, 2004
Standard Test Method for Polyurethane Raw Materials Acidity by Argentometric Determination of Hydrolyzable Chlorine in Monomeric, Aromatic Isocyanates
> 1.1 This test method measures the hydrolyzable chlorine content of monomeric, aromatic isocyanates used as polyurethane raw materials and expresses it as HCl acidity. The test method is applicable...
July 10, 1999
Standard Test Method for Polyurethane Raw Materials Acidity by Argentometric Determination of Hydrolyzable Chlorine in Monomeric, Aromatic Isocyanates
1.1 This test method measures the hydrolyzable chlorine content of monomeric, aromatic isocyanates used as polyurethane raw materials and expresses it as HCl acidity. The test method is applicable to...
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