ASTM International - ASTM D5812-96
Standard Test Method for Determination of Organochlorine Pesticides in Water by Capillary Column Gas Chromatography
|Publication Date:||1 January 1996|
1.1 This test method covers the capillary gas chromatographic determination of various organochlorine pesticides, including some of their degradation products and related compounds in finished drinking water. This test method is not limited to this particular aqueous matrix; however, its applicability to other aqueous matrices must be determined. The tested compounds include the following:
Chemical Abstract Pesticide Service Registry Number A Aldrin 309-00-2 [alpha]-BHC 319-84-6 [beta]-BHC 319-85-7 [gamma]-BHC 319-86-8 [delta]-BHC 58-89-9 [alpha]-Chlordane 5103-71-9 [gamma]-Chlordane 5103-74-2 Chlorobenzilate 501-15-6 Chloroneb 2675-77-6 Chlorothalonil 2921-88-2 DCPA 1897-45-6 4,4'-DDD 72-54-8 4,4'-DDE 72-55-9 4,4'-DDT 50-29-3 Dieldrin 60-57-1 Endosulfan I 959-98-8 Endosulfan II 33213-65-9 Endosulfan sulfate 1031-0708 Endrin 72-20-8 Endrin aldehyde 7421-93-4 Etridiazole 2593-15-9 Heptachlor 76-44-8 Heptachlor epoxide 1024-57-3 Hexachlorobenzene 118-74-1 Methoxychlor 72-43-5 cis-Permethrin 52645-53-1 trans-Permethrin 52645-53-1 Propachlor 1918-16-7 Trifluralin 1582-09-8 A Numbering system of CAS Registry Services, P.O. Box 3343, Columbus, OH 43210-0334.
1.2 Tables 1 and 1 list the applicable concentration ranges and precision and bias statements for this test method. The applicability of this test method to other compounds must be demonstrated.
1.3 The extraction conditions of this test method are comparable to Test Method D3534, which determines commercial polychlorinated biphenyl (PCB) mixtures (Aroclors). The extract derived from this procedure may be analyzed for these constituents by using the gas chromatography (GC) conditions prescribed in either Test Method D3534 (packed column) or Test Method D5175 (capillary column). Although the columns used in this test method may be adequate for analyzing PCBs, no data were collected for any multi-congener constituents during methods development.
1.4 This test method is restricted to use by or under the supervision of analysts experienced in the use of GC and interpretation of gas chromatograms. Each analyst must demonstrate the ability to generate acceptable results using the procedures described in Section 12.
1.5 Analytes that are not separated chromatographically by either the primary or secondary chromatographic columns (for example, analytes having very similar retention times) cannot be identified and measured individually in the same calibration mixture or water sample unless an alternative technique for identification and quantitation exists (see 7.9 and 13.4).
1.6 When this test method is used to analyze unfamiliar samples for any or all of the analytes listed in 1.1, analyte identifications and concentrations should be confirmed by at least one additional technique.
1.7 The values stated in SI units are to be regarded as the standard.
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 9.