ASTM International - ASTM D5576-00(2013)
Standard Practice for Determination of Structural Features in Polyolefins and Polyolefin Copolymers by Infrared Spectrophotometry (FT-IR)
Organization: | ASTM International |
Publication Date: | 1 April 2013 |
Status: | inactive |
Page Count: | 3 |
ICS Code (Thermoplastic materials): | 83.080.20 |
scope:
1.1 This practice covers infrared procedures for determining the molecular structural features in polyolefins and polyolefin copolymers. The structural features of primary concern are the types and numbers of branches. Although this practice centers its attention on polyolefins and polyolefin copolymers, the techniques, with proper modification, can be used for some other polymers as well.
Note 1-Quantitative determinations require either an internal or an external evaluation of sample thickness. ASTM test methods available for specific features are listed in Tables 1 and 2. TABLE 1 Polyolefin Structural Features Determined by FT-IR
Structure | Absorption Band, cm
-1 | ASTM Test Method |
Methyl group (polyethylene) | 1378 |
D2238 |
Methyl group (eth-prop copol) | 1380 | |
Pendant methyl | 935 | |
Terminal vinyl | 908 |
D6248 |
Trans-vinylene | 965 |
D6248 |
Vinylidene | 888 |
D3124 |
TABLE 2 Structural Features in Polyolefin Copolymer Determined by FT-IR
Structure | Absorption Band, cm
-1 | ASTM Test Method |
Vinyl acetate | 609 |
D5594 |
1020 |
D5594 | |
3270 |
D5594 | |
Styrene | 770-700 | |
1600-1500 | ||
Ethyl acrylate | 1640-1730 | |
862 |
D3594 | |
Ethylene acrylate | 1280-1200 | |
1640-1625 |
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and to determine the applicability of the regulatory limitations prior to use.
Note 2-There is no known ISO equivalent to this standard.
abstract:
This practice covers infrared spectrophotometry procedures for determining the molecular structural features such as types and number of branches in polyolefins and polyolefin copolymers. The... View More
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