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ASTM International - ASTM D7845-13

Standard Test Method for Determination of Chemical Species in Marine Fuel Oil by Multidimensional Gas Chromatography – Mass Spectrometry

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Organization: ASTM International
Publication Date: 1 April 2013
Status: inactive
Page Count: 11
ICS Code (Marine engines and propulsion systems): 47.020.20
ICS Code (Liquid fuels): 75.160.20
significance And Use:

5.1 The test method allows the quantitation of chemical species at low levels in marine fuel oils and cutter stocks. A great many types and concentrations of chemical species are found in marine... View More

scope:

1.1 This test method covers the quantitative determination of a variety of chemical species in marine fuel oil (bunker fuel oil) by gas chromatography - mass spectrometry. By using the same conditions and by selecting required mass spectral selected ions, the test method may be used for the determination of other species than those for which precision statements and limits of detection have been established.

1.2 An example list of chemical species for which a limit of quantification has been determined by means of this test method is given in Table 1.

TABLE 1 Component Table

  Limit of Quantitation
mg/kg
n-butyl alcohol 10
Cyclohexanol 10
n-butyl ether 10
n-butyl acylate 10
Styrene 10
alpha-pinene 10
Phenol 20
alpha-methyl styrene 10
beta-pinene 10
4-methyl styrene 10
trans-B-methyl styrene 10
3-methyl styrene 10
2-methyl styrene 10
Dicyclopentadiene 10
Limonene 10
Indene 20
1-phenyl ethanol 20
para, alpha-Dimethyl styrene 20
2,5 dimethyl styrene 20
2,4 dimethyl styrene 20
2-phenyl ethanol (phenylethanol) 20
2-Ethyl Phenol 50
2,4 Dimethyl Phenol 20
4-Ethyl Phenol (co elutes with 3-ethylphenol) 20
2-Phenoxy-1-propanol 50
2-Phenoxy ethanol 50
4-isopropylphenol 50
1-Phenoxy-2-Propanol 20
Styrene Glycol 50

1.3 Other refinery hydrocarbon fractions and their mixtures may be tested using the same test method conditions. However, the precision of this test method reflects the compounds in Table 1.

1.4 Results are reported to the nearest 1.0 mg/kg.

1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Document History

June 15, 2020
Standard Test Method for Determination of Chemical Species in Marine Fuel Oil by Multidimensional Gas Chromatography/Mass Spectrometry
1.1 This test method covers the quantitative determination of a variety of chemical species in marine fuel oil (bunker fuel oil) by gas chromatography/mass spectrometry. By using the same conditions...
January 15, 2017
Standard Test Method for Determination of Chemical Species in Marine Fuel Oil by Multidimensional Gas Chromatography/Mass Spectrometry
1.1 This test method covers the quantitative determination of a variety of chemical species in marine fuel oil (bunker fuel oil) by gas chromatography/mass spectrometry. By using the same conditions...
April 1, 2016
Standard Test Method for Determination of Chemical Species in Marine Fuel Oil by Multidimensional Gas Chromatography/Mass Spectrometry
1.1 This test method covers the quantitative determination of a variety of chemical species in marine fuel oil (bunker fuel oil) by gas chromatography/mass spectrometry. By using the same conditions...
ASTM D7845-13
April 1, 2013
Standard Test Method for Determination of Chemical Species in Marine Fuel Oil by Multidimensional Gas Chromatography – Mass Spectrometry
1.1 This test method covers the quantitative determination of a variety of chemical species in marine fuel oil (bunker fuel oil) by gas chromatography - mass spectrometry. By using the same...
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