ASTM International - ASTM G67-04
Standard Test Method for Determining the Susceptibility to Intergranular Corrosion of 5XXX Series Aluminum Alloys by Mass Loss After Exposure to Nitric Acid (NAMLT Test) (Withdrawn 2013)
|Publication Date:||1 May 2004|
|ICS Code (Chemical analysis of metals):||77.040.30|
|ICS Code (Aluminium and aluminium alloys):||77.120.10|
significance And Use:
This test method provides a quantitative measure of the susceptibility to intergranular corrosion of Al-Mg and Al-Mg-Mn alloys. The nitric acid dissolves a second phase, an aluminum-magnesium... View More
This test method provides a quantitative measure of the susceptibility to intergranular corrosion of Al-Mg and Al-Mg-Mn alloys. The nitric acid dissolves a second phase, an aluminum-magnesium intermetallic compound (βAl-Mg), in preference to the solid solution of magnesium in the aluminum matrix. When this compound is precipitated in a relatively continuous network along grain boundaries, the effect of the preferential attack is to corrode around the grains, causing them to fall away from the specimens. Such dropping out of the grains causes relatively large mass losses of the order of 25 to 75 mg/cm2 (160 to 480 mg/in2), whereas, samples of intergranular-resist
The precipitation of the second phase in the grain boundaries also gives rise to intergranular corrosion when the material is exposed to chloride-containing natural environments, such as seacoast atmospheres or sea water. The extent to which the alloy will be susceptible to intergranular corrosion depends upon the degree of precipitate continuity in the grain boundaries. Visible manifestations of the attack may be in various forms such as pitting, exfoliation, or stress-corrosion cracking, depending upon the morphology of the grain structure and the presence of sustained tensile stress.3View Less
1.1 This test method describes a procedure for constant immersion intergranular corrosion testing of 5XXX series aluminum alloys.
1.2 This test method is applicable only to wrought products.
1.3 This test method covers type of specimen, specimen preparation, test environment, and method of exposure.
1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.